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Beilstein J. Org. Chem. 2022, 18, 872–880, doi:10.3762/bjoc.18.88
Graphical Abstract
Scheme 1: Electrochemical gem-difluorination of sulfides bearing α-electron-withdrawing groups.
Scheme 2: Electrochemical gem-difluorodesulfurization of dithioacetals.
Scheme 3: Electrochemical gem-difluorodesulfurization of dithiocarbonate.
Scheme 4: Cathodic reduction of 1.
Figure 1: Cyclic voltammograms of (a) PhSCF2Br (1, 8 mM) in 0.1 M n-Bu4NClO4/MeCN; (b) o-phthalonitrile (4 mM...
Scheme 5: Indirect cathodic reduction of 1 using o-phthalonitrile as mediator.
Scheme 6: Mechanism for the formation of product 3.
Scheme 7: Reaction of compound 1 with PhS anions.
Scheme 8: Cathodic reduction of compound 1 in the presence of α-methylstyrene at a high current density.
Scheme 9: Indirect cathodic reduction of compound 1 in CD3CN.
Scheme 10: Indirect cathodic reduction of compound 1 in the presence of 1,1-diphenylethylene.
Scheme 11: Reaction mechanism.